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Technical Paper

Accurate Measurements of Heat Release, Oxidation Rates, and Soluble Organic Compounds of Diesel Particulates through Thermal Reactions

2010-04-12
2010-01-0814
In an effort of providing better understanding of regeneration mechanisms of diesel particulate matter (PM), this experimental investigation focused on evaluating the amount of heat release generated during the thermal reaction of diesel PM and the concentrations of soluble organic compounds (SOCs) dissolved in PM emissions. Differences in oxidation behaviors were observed for two different diesel PM samples: a SOC-containing PM sample and a dry soot sample with no SOCs. Both samples were collected from a cordierite particulate filter membrane in a thermal reactor connected to the exhaust pipe of a light-duty diesel engine. A differential scanning calorimeter (DSC) and a thermogravimetric analyzer (TGA) were used to measure the amount of heat release during oxidation, along with subsequent oxidation rates and the concentrations of SOCs dissolved in particulate samples, respectively.
Journal Article

Achieving Diesel Powertrain Ownership Parity in Battery Electric Heavy Duty Commercial Vehicles Using a Rapid Recurrent Recharging Architecture

2022-03-29
2022-01-0751
Battery electric vehicles (BEV) in heavy duty (HD) commercial freight transport face challenging technoeconomic barriers to adoption. Specifically, beyond safety and compliance, fleet and operational logistics require both high up-time and parity with diesel system productivity/Total Cost of Ownership (TCO) to enable strong adoption of electrified powertrains. At present, relatively high energy storage prices coupled with the increased weight of BEV systems limit the practicality of HD commercial freight transport to shorter range applications, where smaller batteries will suffice for the mission energy requirements (single operational shift). This paper presents an approach to extend the feasibility of BEV HD trucking for a broad range of applications.
Technical Paper

Advanced Automatic Transmission Model Validation Using Dynamometer Test Data

2014-04-01
2014-01-1778
As a result of increasingly stringent regulations and higher customer expectations, auto manufacturers have been considering numerous technology options to improve vehicle fuel economy. Transmissions have been shown to be one of the most cost-effective technologies for improving fuel economy. Over the past couple of years, transmissions have significantly evolved and impacted both performance and fuel efficiency. This study validates the shifting control of advanced automatic transmission technologies in vehicle systems by using Argonne National Laboratory's model-based vehicle simulation tool, Autonomie. Different midsize vehicles, including several with automatic transmission (6-speeds, 7-speeds, and 8-speeds), were tested at Argonne's Advanced Powertrain Research Facility (APRF). For the vehicles, a novel process was used to import test data.
Technical Paper

Advanced Materials Characterization at the High Temperature Materials Laboratory

1999-04-28
1999-01-2256
The HTML (High Temperature Materials Laboratory) is a U.S. Department of Energy User Facility, offering opportunities for in-depth characterization of advanced materials, specializing in high-temperature-capable structural ceramics. Available are electron microscopy for micro-structural and microchemical analysis, equipment for measurement of the thermophysical and mechanical properties of ceramics to elevated temperatures, X-ray and neutron diffraction for structure and residual stress analysis, and high speed grinding machines with capability for measurement of component shape, tolerances, surface finish, and friction and wear properties. This presentation will focus on structural materials characterization, illustrated with examples of work performed on heat engine materials such as silicon nitride, industrial refractories, metal-and ceramic-matrix composites, and structural alloys.
Technical Paper

Air-to-Fuel Ratio Calculation Methods for Oxygenated Fuels in Two-Stroke Engines

2015-04-14
2015-01-0965
In 1990, Roy Douglas developed an analytical method to calculate the global air-to-fuel ratio of a two-stroke engine from exhaust gas emissions. While this method has considerable application to two-stroke engines, it does not permit the calculation of air-to-fuel ratios for oxygenated fuels. This study proposed modifications to the Roy Douglas method such that it can be applied to oxygenated fuels. The ISO #16183 standard, the modified Spindt method, and the Brettschneider method were used to evaluate the modifications to the Roy Douglas method. In addition, a trapped air-to-fuel ratio, appropriate for two-stroke engines, was also modified to incorporate oxygenated fuels. To validate the modified calculation method, tests were performed using a two-stroke carbureted and two-stroke direct injected marine outboard engine over a five-mode marine test cycle running indolene and low level blends of ethanol and iso-butanol fuels.
Journal Article

Ammonia Generation and Utilization in a Passive SCR (TWC+SCR) System on Lean Gasoline Engine

2016-04-05
2016-01-0934
Lean gasoline engines offer greater fuel economy than the common stoichiometric gasoline engine, but the current three way catalyst (TWC) on stoichiometric engines is unable to control nitrogen oxide (NOX) emissions in oxidizing exhaust. For these lean gasoline engines, lean NOX emission control is required to meet existing Tier 2 and upcoming Tier 3 emission regulations set by the U.S. Environmental Protection Agency (EPA). While urea-based selective catalytic reduction (SCR) has proven effective in controlling NOX from diesel engines, the urea storage and delivery components can add significant size and cost. As such, onboard NH3 production via a passive SCR approach is of interest. In a passive SCR system, NH3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean operation, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst.
Journal Article

Ammonia Generation over TWC for Passive SCR NOX Control for Lean Gasoline Engines

2014-04-01
2014-01-1505
A commercial three-way catalyst (TWC) was evaluated for ammonia (NH3) generation on a 2.0-liter BMW lean burn gasoline direct injection engine as a component in a passive ammonia selective catalytic reduction (SCR) system. The passive NH3 SCR system is a potential low cost approach for controlling nitrogen oxides (NOX) emissions from lean burn gasoline engines. In this system, NH3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst. NH3 generation was evaluated at different air-fuel equivalence ratios at multiple engine speed and load conditions. Near complete conversion of NOX to NH3 was achieved at λ=0.96 for nearly all conditions studied. At the λ=0.96 condition, HC emissions were relatively minimal, but CO emissions were significant.
Technical Paper

Ammonia Production and Utilization in a Hybrid LNT+SCR System

2009-11-02
2009-01-2739
A hybrid LNT+SCR system is used to control NOx from a light-duty diesel engine with in-cylinder regeneration controls. A diesel oxidation catalyst and diesel particulate filter are upstream of the LNT and SCR catalysts. Ultraviolet (UV) adsorption spectroscopy performed directly in the exhaust path downstream of the LNT and SCR catalysts is used to characterize NH3 production and utilization in the system. Extractive exhaust samples are analyzed with FTIR and magnetic sector mass spectrometry (H2) as well. Furthermore, standard gas analyzers are used to complete the characterization of exhaust chemistry. NH3 formation increases strongly with extended regeneration (or “over regeneration”) of the LNT, but the portion of NOx reduction occurring over the SCR catalyst is limited by the amount of NH3 produced as well as the amount of NOx available downstream of the LNT. Control of lean-rich cycling parameters enables control of the ratio of NOx reduction between the LNT and SCR catalysts.
Technical Paper

An Analytical Energy-budget Model for Diesel Droplet Impingement on an Inclined Solid Wall

2020-04-14
2020-01-1158
The study of spray-wall interaction is of great importance to understand the dynamics that occur during fuel impingement onto the chamber wall or piston surfaces in internal combustion engines. It is found that the maximum spreading length of an impinged droplet can provide a quantitative estimation of heat transfer and energy transformation for spray-wall interaction. Furthermore, it influences the air-fuel mixing and hydrocarbon and particle emissions at combusting conditions. In this paper, an analytical model of a single diesel droplet impinging on the wall with different inclined angles (α) is developed in terms of βm (dimensionless maximum spreading length, the ratio of maximum spreading length to initial droplet diameter) to understand the detailed impinging dynamic process.
Technical Paper

An Assessment of Electric Vehicle Life Cycle Costs to Consumers

1998-11-30
982182
A methodology for evaluating life cycle cost of electric vehicles (EVs) to their buyers is presented. The methodology is based on an analysis of conventional vehicle costs, costs of drivetrain and auxiliary components unique to EVs, and battery costs. The conventional vehicle's costs are allocated to such subsystems as body, chassis, and powertrain. In electric vehicles, an electric drive is substituted for the conventional powertrain. The current status of the electric drive components and battery costs is evaluated. Battery costs are estimated by evaluating the material requirements and production costs at different production levels; battery costs are also collected from other sources. Costs of auxiliary components, such as those for heating and cooling the passenger compartment, are also estimated. Here, the methodology is applied to two vehicle types: subcompact car and minivan.
Technical Paper

An Estimate of Diesel High-Efficiency Clean Combustion Impacts on FTP-75 Aftertreatment Requirements

2006-10-16
2006-01-3311
A modified Mercedes 1.7-liter, direct-injection diesel engine was operated in both normal and high-efficiency clean combustion (HECC) combustion modes. Four steady-state engine operating points that were previously identified by the Ad-hoc fuels working group were used as test points to allow estimation of the hot-start FTP-75 emissions levels in both normal and HECC combustion modes. The results indicate that operation in HECC modes generally produce reductions in NOX and PM emissions at the expense of CO, NMHC, and H2CO emissions. The FTP emissions estimates indicate that aftertreatment requirements for NOX are reduced, while those for PM may not be impacted. Cycle-average aftertreatment requirements for CO, NMHC, and H2CO may be challenging, especially at the lowest temperature conditions.
Technical Paper

An Examination of Spray Stochastics in Single-Hole Diesel Injectors

2015-09-01
2015-01-1834
Recent advances in x-ray spray diagnostics at Argonne National Laboratory's Advanced Photon Source have made absorption measurements of individual spray events possible. A focused x-ray beam (5×6 μm) enables collection of data along a single line of sight in the flow field and these measurements have allowed the calculation of quantitative, shot-to-shot statistics for the projected mass of fuel sprays. Raster scanning though the spray generates a two-dimensional field of data, which is a path integrated representation of a three-dimensional flow. In a previous work, we investigated the shot-to-shot variation over 32 events by visualizing the ensemble standard deviations throughout a two dimensional mapping of the spray. In the current work, provide further analysis of the time to steady-state and steady-state spatial location of the fluctuating field via the transverse integrated fluctuations (TIF).
Technical Paper

An Investigation of Grid Convergence for Spray Simulations using an LES Turbulence Model

2013-04-08
2013-01-1083
A state-of-the-art spray modeling methodology, recently applied to RANS simulations, is presented for LES calculations. Key features of the methodology, such as Adaptive Mesh Refinement (AMR), advanced liquid-gas momentum coupling, and improved distribution of the liquid phase, are described. The ability of this approach to use cell sizes much smaller than the nozzle diameter is demonstrated. Grid convergence of key parameters is verified for non-evaporating and evaporating spray cases using cell sizes down to 1/32 mm. It is shown that for global quantities such as spray penetration, comparing a single LES simulation to experimental data is reasonable, however for local quantities the average of many simulated injections is necessary. Grid settings are recommended that optimize the accuracy/runtime tradeoff for LES-based spray simulations.
Technical Paper

An Investigation of Particulate Morphology, Microstructures, and Fractal Geometry for ael Diesel Engine-Simulating Combustor

2004-10-25
2004-01-3044
The particulate matter (PM) produced from a diesel engine-simulating combustor was characterized in its morphology, microstructure, and fractal geometry by using a unique thermophoretic sampling and Transmission Electron Microscopy (TEM) system. These results revealed that diesel PM produced from the laboratory-scale burner showed similar morphological characteristics to the particulates produced from diesel engines. The flame air/fuel ratio and the particulate temperature history have significant influences on both particle size and fractal geometry. The primary particle sizes were measured to be 14.7 nm and 14.8 nm under stoichiometric and fuel-rich flame conditions, respectively. These primary particle sizes are smaller than those produced from diesel engines. The radii of gyration for the aggregate particles were 83.8 nm and 47.5 nm under these two flame conditions.
Technical Paper

An Optical Backscatter Sensor for Particulate Matter Measurement

2009-04-20
2009-01-0687
An optical-based sensor for detecting particulate matter (PM) in diesel engine exhaust has been demonstrated. The position of the sensor during the experiments was the exhaust manifold prior to the turbocharger. The sensor is constructed of fiber optics which transmit 532-nm laser light into the exhaust pipe and collect backscattered light in a 180° geometry. Due to the optical nature of the probe, PM sensing can occur at high temporal rates. Experiments conducted by changing the fuel injection properties of one cylinder of a four cylinder engine demonstrated that the sensor can resolve cycle dependent events. The feasibility of the probe for examining PM emissions in the exhaust manifold will be discussed.
Technical Paper

An Overview of ARES Research

2011-01-19
2011-26-0085
With an intention to improve the performance of reciprocating engines used for distributed generation US-Dept. of Energy has launched ARES program. Under this program, the performance targets for these natural gas-fuelled stationary engines are ≻ 50% efficiency and NOx emissions ≺ 0.1 g/bhp-hr by 2013. This paper presents two technologies developed under this program. Lean-burn operation is very popular with engine manufacturers as it offers simultaneous low-NOx emissions and high engine efficiencies, while not requiring the use of any aftertreatment devices. Though engines operating on lean-burn operation are capable of better performance, they are currently limited by the inability to sustain reliable ignition under lean conditions. Addressing such an issue, research has evaluated the use of laser ignition as an alternative to the conventional Capacitance Discharge Ignition (CDI).
Technical Paper

Analysis and Model Validation of the Toyota Prius Prime

2019-04-02
2019-01-0369
The Toyota Prius Prime is a new generation of Toyota Prius plug-in hybrid electric vehicle, the electric drive range of which is 25 miles. This version is improved from the previous version by the addition of a one-way clutch between the engine and the planetary gear-set, which enables the generator to add electric propulsive force. The vehicle was analyzed, developed and validated based on test data from Argonne National Laboratory’s Advanced Powertrain Research Facility, where chassis dynamometer set temperature can be controlled in a thermal chamber. First, we analyzed and developed components such as engine, battery, motors, wheels and chassis, including thermal aspects based on test data. By developing models considering thermal aspects, it is possible to simulate the vehicle driving not only in normal temperatures but also in hot, cold, or warmed-up conditions.
Technical Paper

Analysis of Fast Charging Station Network for Electrified Ride-Hailing Services

2018-04-03
2018-01-0667
Today’s electric vehicle (EV) owners charge their vehicles mostly at home and seldom use public direct current fast charger (DCFCs), reducing the need for a large deployment of DCFCs for private EV owners. However, due to the emerging interest among transportation network companies to operate EVs in their fleet, there is great potential for DCFCs to be highly utilized and become economically feasible in the future. This paper describes a heuristic algorithm to emulate operation of EVs within a hypothetical transportation network company fleet using a large global positioning system data set from Columbus, Ohio. DCFC requirements supporting operation of EVs are estimated using the Electric Vehicle Infrastructure Projection tool. Operation and installation costs were estimated using real-world data to assess the economic feasibility of the recommended fast charging stations.
Journal Article

Analysis of Input Power, Energy Availability, and Efficiency during Deceleration for X-EV Vehicles

2013-04-08
2013-01-1473
The recovery of braking energy through regenerative braking is a key enabler for the improved efficiency of Hybrid Electric Vehicles, Plug-in Hybrid Electric, and Battery Electric Vehicles (HEV, PHEV, BEV). However, this energy is often treated in a simplified fashion, frequently using an overall regeneration efficiency term, ξrg [1], which is then applied to the total available braking energy of a given drive-cycle. In addition to the ability to recapture braking energy typically lost during vehicle deceleration, hybrid and plug-in hybrid vehicles also allow for reduced or zero engine fueling during vehicle decelerations. While regenerative braking is often discussed as an enabler for improved fuel economy, reduced fueling is also an important component of a hybrid vehicle's ability to improve overall fuel economy.
Technical Paper

Analysis of Life Cycle Costs for Electric Vans with Advanced Battery Systems

1989-02-01
890819
The performance of advanced Zn/Br2, LiAl/FeS, Na/S, Ni/Fe, and Fe/Air batteries in electric vans was compared to that of tubular lead-acid technology. The MARVEL computer analysis system evaluated these batteries for the G-Van and IDSEP vehicles over two driving schedules. Each of the advanced batteries exhibited the potential for major improvements in both range and life cycle cost compared with tubular lead-acid. A sensitivity analysis revealed specific energy, battery initial cost, and cycle life to be the dominant factors in reducing life cycle cost for the case of vans powered by tubular lead-acid batteries.
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